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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_86e773779a33e03c35ed6cf392b1c96b
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publicationDate 2015-09-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2015137836-A1
titleOfInvention Process of fabrication of crystalline nanometric lithium transition metal phosphate
abstract A process of fabrication of nanometric lithium transition metal phosphate with the general formula LiMPO 4 , where M denotes a metal ion or mixture of metal ions from a group comprising Fe, Mn, Co and Ni, particularly lithium iron(ll) phosphate, LiFePO 4 , by co-precipitation of nanometric powder from a boiling aqueous solution with the addition of organic liquids containing Li + , M 2+ and PO 4 n 3- ions, which after filtering, washing with water and alcohol, is characterised by the fact that a reducing agent in the amount of 10 to 100 mol.% in relation to transition metal ions is introduced to the solution containing at least one of the ions selected from a group comprising Li + , M 2+ , PO 4 n 3- , and/or a reducing gas mixture is passed through the solution. At least one of the following agents is applied as a reducing agent: potassium iodide, ammonium thiosulphate, glucose, ascorbic acid, tin(ll) chloride.
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