Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_33b011e77b33662b8bf1f2ff2de7b661 |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-0258 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-582 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-842 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1815 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-184 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-93 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-29 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B33-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G16C20-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D493-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-025 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-18 |
filingDate |
2014-09-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_46b5bc1b39af2b430471d104e2b5a726 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a4bbbfd4665cdb5ce3a7584c73aa1329 |
publicationDate |
2015-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
WO-2015035412-A1 |
titleOfInvention |
Catalyst-controlled aliphatic c-h oxidations |
abstract |
The invention provides simple small molecule, non-heme iron catalyst systems with broad substrate scope that can predictably enhance or overturn a substrate's inherent reactivity preference for sp3-hybridized C-H bond oxidation. The invention also provides methods for selective aliphatic C-H bond oxidation. Furthermore, a structure-based catalyst reactivity model is disclosed that quantitatively correlates the innate physical properties of the substrate to the site-selectivities observed as a function of the catalyst. The catalyst systems can be used in combination with oxidants such as hydrogen peroxide to effect highly selective oxidations of unactivated sp3 C-H bonds over a broad range of substrates. |
priorityDate |
2013-09-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |