| Predicate |
Object |
| assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c5520dd38cc403678d9f91e0b0ee95fb |
| classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2261-37
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2261-312
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2261-344
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2261-3328
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2261-18
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2261-135 |
| classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G83-008
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G79-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G61-124 |
| classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G61-12 |
| filingDate |
2014-06-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f39431e0ce4ca304397801346e156198
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4a230ec4feeafce873c4ff671ff6ecbb |
| publicationDate |
2014-12-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber |
WO-2014208407-A1 |
| titleOfInvention |
Facile synthesis of metalloporphyrin polymers |
| abstract |
A method is provided for synthesizing a metal (M) meso-tetraphenylporphyrin polymer. The method begins with the provision of a free-base (H 2 ) -meso-tetra-4- ( trialkylsilyl) ethynylphenylporphyrin (H 2 -tetra-C≡C-TriAS- TPP) including a trialkylsilyl (TriAS) moiety attached to an ethynyl termini. In response to a reaction with a metal (M) - containing material, the H 2 -tetra-C≡C-TriAS-TPP is converted to a metal (M) -tetra-4- (trialkylsilyl)ethynylphenylporphyrin (M-tetra-C≡C-TriAS- TPP). Then, the M-tetra-C≡C-TriAS-TPP is converted to a M-tetra-4-ethynylphenylporphyrin (M-tetra-C≡C-TPP) monomer by removing the trialkylsilyl (TriAS) moiety from the ethynyl termini. Finally, a plurality of M-tetra-C≡C-TPP monomers are coupled together to supply a metal (M) -meso- tetraphenylporphyrin polymer (M-poly-meso-TPP), whereby meso-phenyl groups of adjacent M-tetra-C≡C-TPP monomers in the M-poly-meso-TPP are connected through a butadiyne linking moiety. In one aspect, the metal is zinc. |
| isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111019096-B
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-111019096-A
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-105777764-B
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-105777764-A |
| priorityDate |
2013-06-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type |
http://data.epo.org/linked-data/def/patent/Publication |