http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2014118854-A1

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publicationDate 2014-08-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2014118854-A1
titleOfInvention Transition metal hexacyanoferrate battery cathode, transition metal hexacyanoferrate cathode battery, method for synthesizing a transition metal hexacyanoferrate battery material, method for fabricating a transition metal hexacyanoferrate battery cathode electrode, and method for using a transition metal hexacyanoferrate battery
abstract A transition metal hexacyanoferrate (TMH) cathode battery is provided. The battery has a A x Mn[Fe(CN) 6 ] y n . zH 2 O cathode, where the A cations are either alkali or alkaline-earth cations, such as sodium or potassium, where x is in the range of 1 to 2, where y is in the range of 0.5 to 1, and where z is in the range of 0 to 3.5. The A x Mn[Fe(CN) 6 ] y n . zH 2 O has a rhombohedral crystal structure with Mn 2+/3+ and Fe 2+/3+ having the same reduction/oxidation potential. The battery also has an electrolyte, and anode made of an A metal, an A composite, or a material that can host A atoms. The battery has a single plateau charging curve, where a single plateau charging curve is defined as a constant charging voltage slope between 15% and 85% battery charge capacity. Fabrication methods are also provided.
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