http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2014089303-A1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_02fc8b0aa7fd88c3eb85c0889572d326 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-322 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-847 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-90 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C253-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C253-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C253-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-185 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C253-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-18 |
filingDate | 2013-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_84edbe7d08f90d67a48e8adb3cc92ba1 |
publicationDate | 2014-06-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | WO-2014089303-A1 |
titleOfInvention | Improved process for producing pentenenitriles |
abstract | The invention provides methods useful in the industrial scale process for hydrocyanation of butadiene to adiponitrile for recycle of unwanted byproduct 2-methyl-3-butenenitrile (2M3BN) by conversion to process intermediate pentenenitrile. The invention provides a process for generating catalysts useful for carrying out the hydrocyanation of butadiene to adiponitrile, the process comprising contacting the 2M3BN and a solution of a nickel-ligand catalyst in cis-2-pentenenitrile (cis-2PN), trans-2-pentenenitrile (trans-2PN), or a mixture thereof. The improved methods of the invention can provide improved catalyst solubility for bidentate ligands without a requirement for a Lewis acid catalyst promoter such as zinc chloride to be present. |
priorityDate | 2012-12-07-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 270.