http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2014055485-A1

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publicationDate 2014-04-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2014055485-A1
titleOfInvention GRAPHENE - Co/CoO NANOPARTICLE COMPOSITE, MANUFACTURE, AND USE IN AN ELECTROCHEMICAL CELL
abstract The synthesis and self-assembly of core/shell Co/CoO nanoparticles (NPs) onto the surface of graphene (G) as a catalyst for electrocatalytic reduction of oxygen in alkaline media. The Co NPs are first synthesized and then oxidized in a controlled environment to add a Cobalt oxide shell, forming core/shell Co/CoO NPs with shell thickness tunable from 1-3 nm. Compared to G, and to carbon supported Co/CoO (C-Co/CoO) NPs, the G-Co/CoO NPs show enhanced catalytic activity in O 2 -saturated 0.1 M KOH solution. Fabrication of monodisperse ten nm particles with a 1 nm thick oxide shell on graphene exhibited activity comparable to, and stability better than, a commercial C-Pt NP catalyst. The nanoparticle composite is thus a promising candidate for high performance inexpensive fuel cells and batteries using an oxygen reduction reaction in alkaline solutions.
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