http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2014008799-A1

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filingDate 2013-06-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_72aa2849004187ddc0df8b0fe1a6118a
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publicationDate 2014-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2014008799-A1
titleOfInvention Block copolymer containing block with glass transition temperature higher than 100°c and method of production thereof
abstract Disclosed are a block copolymer containing a block with the glass transition temperature higher than 100°C and a method for preparing the block copolymer. In the method, the block copolymer latex is prepared by taking n-butyl acrylate as a soft segment and the random copolymer of styrene and gamma-methyl-alpha-methylene-gamma-butyrolactone as a hard segment, adopting an emulsion polymerization system and applying a reversible addition-fragmentation chain transfer free radical polymerization technology. The method adopts simple processes and equipment, and the processes are environmental-friendly and energy-saving; an amphipathic macromolecule reversible addition-fragmentation chain transfer reagent is adopted, has the dual functions of both a chain transfer reagent and an emulsifier, not only is the good monomer polymerization control realized, but also the traditional emulsifier is prevented from being used; the reaction has no inhibition period, the reaction speed is high and the final conversion rate is high; the colloidal particles are stably increased during the process; and the glass transition temperature of the hard segment of the product can reach 155°C, and the block copolymer has a good application prospect in the field of high-heat-resistance thermoplastic elastomers.
priorityDate 2012-07-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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