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filingDate 2012-09-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_20830b2ebba7728f38b944e4b90e03bd
publicationDate 2013-04-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2013047494-A1
titleOfInvention Highly accurate correlating method for phase equilibrium data, and phase balance calculation method
abstract Provided are: a method for accurately deriving phase equilibrium from existing phase equilibrium data for wide-ranging phase equilibrium data including 2-component system vapor-liquid equilibrium data; a method and device for designing and controlling the isolation and refining of components using said method; and a device designing program for designing these design or control devices. Using a 2-component system phase equilibrium measurement data, the critical point carryover factor X represented by formula (22) below and infinite dilution pressure gradient Y 1 and Y 2 represented by formulas (24) and (25) are calculated (in the formula, P c1 is the critical pressure of component 1 in the 2-component system, p 1s and p 2s are the vapor pressures of component 1 and component 2 respectively at temperature T, and γ i n ∞ represents the infinite dilution activity coefficient with respect to the component i in liquid phase), the X and Y 1 and Y 2 are correlated, new infinite dilution activity coefficient γ 1 n ∞ , γ 2 n ∞ or 2 component system parameters A, B are calculated from the X-Y 1 correlation and X-Y 2 , and phase equilibrium is calculated from the obtained γ 1 n ∞ and γ 2 n ∞ or from A and B. The design and control of component isolation and refining devices, such as distillation columns, is carried out using values thus obtained. Critical point arrival rate X: (22) infinite dilution pressure gradient Y 1 and Y 2 : (24), (25)
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priorityDate 2011-09-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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