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filingDate 2012-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_331e1dc746185f0cf166138ff5084348
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publicationDate 2012-08-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2012112264-A1
titleOfInvention Heat-treated ziegler-natta catalysts for ethylene polymerization
abstract Catalyst systems, processes of forming the same and polymers formed therefrom are described herein. The processes of forming the catalyst systems generally include contacting a blend of an alkyl magnesium compound and an organoaluminum compound with an alcohol to form a magnesium dialkoxide compound; contacting the magnesium dialkoxide compound with a first agent to form a solution of reaction product "A", the first agent including a halogenating/titanating agent; contacting the solution of reaction product "A" with a second agent to form a solid reaction product "B", the second agent including a blend of a first metal halide and a metal alkoxide; contacting the solid reaction product "B" with a third agent to form a solid reaction product "C, the third agent including a second metal halide; contacting the solid reaction product "C" with a fourth agent to form a solid reaction product "D".
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