abstract |
Disclosed is a dehydrogenation method that includes supplying a feed containing a hydrocarbon and steam into a dehydrogenation reactor containing a dehydrogenation catalyst, contacting the hydrocarbon and steam with the dehydrogenation catalyst to form a dehydrogenation product, wherein the dehydrogenation product comprises a dehydrogenated hydrocarbon, unreacted feed, steam and hydrogen, passing the dehydrogenation product through a membrane separator, and permeating hydrogen through a membrane positioned in the membrane separator. The hydrocarbon can be an alkyl aromatic and the dehydrogenated hydrocarbon can be a vinyl aromatic hydrocarbon, optionally the hydrocarbon can be an alkane and the dehydrogenated hydrocarbon can be an alkene. |