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filingDate 2011-12-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2012-07-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2012097920-A1
titleOfInvention Method and device for reducing nitrosamines which form during removal of co2 from flue gases using an aqueous amine solution
abstract The invention relates to a method for reducing nitrosamines which form during removal of CO 2 from flue gases using an aqueous amine solution. According to the invention a subquantity of the aqueous amine solution that is loaded with nitrosamines is branched off from a scrubbing liquid circuit and concentrated by vaporizing water and low-boiling constituents. The concentrated amine solution stays at boiling temperature in an apparatus in which a liquid phase and a vaporous phase are in contact and a vapour/liquid equilibrium is established between the phases. The vaporous phase is irradiated with UV light within the apparatus, which UV light decomposes nitrosamines transferring to the vaporous phase. The concentrated amine solution is returned to the scrubbing liquid circuit after the treatment in the apparatus. The invention also relates to a plant for carrying out the method.
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