http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2011095140-A1

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filingDate 2010-11-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d593331c1e0cc00976ebc54a718dc0fb
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publicationDate 2011-08-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2011095140-A1
titleOfInvention Method of manufacture of zeolites with pentasil structure with controlled distribution of aluminium atoms in the skeleton
abstract The invention relates to a method of manufacture of microporous zeolites with pentasil structure with controlled distribution of aluminium atoms in an alumino-silicate tetrahedrally coordinated skeleton in "A1 pairs" in (A1-O-(Si-O) n=1,2 -A1) sequences localized in a single ring and in different rings in A1-O-(Si-O) n>2 -A1 sequences. Different distribution of Al atoms in alumino-silicate skeleton is achieved by hydrothermal synthesis using a suitable combination of sources of silicon and aluminium, utilizing their different reactivity, presence of alkaline metal salts, and the use of silicate or alumino-silicate amorphous nano-dimensioned precursors with controlled reactivity, seeding crystals and different times of ageing of the reaction mixture. Skeleton of zeolites with pentasil structure with a molar ratio of Si : A1 = 8 : 1 to 40 : 1 contains 5 to 85 % aluminium atoms in the form of A1 pairs and 15 to 95 % of aluminium atoms in the form of isolated A1 atoms. ˙
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