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publicationDate 2011-05-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2011052065-A1
titleOfInvention Process and system for purification of tetrahydrofuran
abstract A process for the purification of tetrahydrofuran from a fluid that contains tetrahydrofuran and includes at least water, dihydrofuran, and butanol as impurities, which comprises: a first distillation step of subjecting the fluid to distillation using a distillation column and thereby separating the fluid into first bottoms containing water as the main component and a first overhead containing tetrahydrofuran, dihydrofuran and butanol as the main components; a second distillation step of subjecting the first overhead to distillation using another distillation column and thereby separating the first overhead into second bottoms containing tetrahydrofuran and butanol as the main components and a second overhead containing dihydrofuran as the main component; and a third distillation step of subjecting the second bottoms to distillation using another distillation column and thereby separating the second bottoms into third bottoms containing butanol as the main component and a third overhead containing tetrahydrofuran as the main component, characterized by further comprising a refluxing step of returning a part of the second overhead to the first distillation step as a reflux liquid and discharging the remainder thereof to the outside of the system.
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