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filingDate 2010-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d52604b41fd8b491ab803f0302893a96
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publicationDate 2011-05-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2011017341-A3
titleOfInvention Ladder-type oligo-p-phenylene-containing copolymers with high open-circuit voltages and ambient photovoltaic activity
abstract Ladder-type oligo- p -phenylene containing donor-acceptor copolymers are disclosed. The ladder-type oligo-p-phenylene can be used as an electron donor unit in the disclosed copolymers to provide a deeper highest occupied molecular orbital (HOMO) level for obtaining polymeric solar cells having a higher open-circuit voltage. Particular electron-accepting units, e.g., a divalent fused-ring heterocyclic moiety selected from the group consisting of a substituted or unsubstituted benzothiadiazole, a substituted or unsubstituted quinoxaline, a substituted or unsubstituted benzobisthiazole, and a substituted or unsubstituted naphthothiadiazole, can be used to tune the electronic band gaps of the polymers for a better light harvesting ability. The disclosed copolymers exhibit field-effect mobilities as high as 0.011 cm 2 /(V s). Compared to fluorene-containing copolymers with the same acceptor unit, the disclosed ladder-type oligo- p -phenylene containing copolymers have enhanced and bathochromically shifted absorption bands and much better solubility in organic solvents.
priorityDate 2009-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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