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filingDate 2008-09-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5ebbc494190252903c651c036f7bfd90
publicationDate 2009-04-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2009047445-A1
titleOfInvention Method for the synthesis of omega-unsaturated fatty acids
abstract The invention relates to a method for the synthesis of short-chain ?-unsaturated fatty acids of the general formula CH2=CH-(CH2)n-COOR, in which n is an integer between 2 and 11 and R is H or an alkyl radical with 1 to 4 carbon atoms, from long-chain mono-unsaturated fatty acids or esters of the formula CH3-(CH2)m-CH=CH-(CH2)p-COOR in which m and p are integers either identical or different between 2 and 11, such that the molecule includes at least 10 adjacent carbon atoms in the main chain, wherein said method comprises the first step of submitting the long-chain mono-unsaturated fatty acid charge to an oxidation by fermentation using a micro-organism containing enzymes of the oxygenase type, thus leading to the formation of a-? diacids, and the second step of submitting the product from the first step to a catalytic metathesis crossed with ethylene for forming two short-chain ?-unsaturated fatty acids having a main chain length relative to that of the starting unsaturated fatty acid or ester of between 0.2 and 0.8, preferably 0.35 and 0.75.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9382189-B2
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