abstract |
Heat shrinkable oriented multilayer films are disclosed that comprise a structural layer, a heat sealing layer and a gas barrier layer. The structural layer comprises a polymer selected from the group consisting of copolymers of ethylene and a C?3#191 to C?8#191 ,-ethylenically unsaturated carboxylic acid, ionomers of the copolymers, polyesters, and blends thereof. The heat sealing layer comprises a polymer selected from the group consisting of ethylene vinyl acetate copolymers, ethylene alkyl acrylate copolymers, ethylene alkyl methacrylate copolymers, polyethylene, and blends thereof. The barrier layer, which is positioned between the structural and heat sealing layer, comprises at least one ethylene vinyl alcohol copolymer that has from about 2 to about 8 mol% 1,2-glycol structural units incorporated in the copolymer backbone chain. The films are particularly suitable for use in manufacture of shrinkbags. |