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filingDate 2006-02-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_814692e3c32ae93b7c0b442d679b2505
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publicationDate 2006-08-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2006084891-A1
titleOfInvention Process for the carbonylation of a conjugated diene
abstract A process for the carbonylation of a conjugated diene to an ethylenically unsaturated acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture comprising an ethylenically unsaturated acid and a reversible diene adduct comprising alkenyl ester of the conjugated diene with the ethylenically unsaturated acid; (b) separating the obtained reaction mixture into a gaseous stream comprising unreacted conjugated diene and carbon monoxide, a first liquid product stream comprising at least part of the ethylenically unsaturated acid and the reversible diene adducts, and a second liquid stream comprising the catalyst system in admixture with the ethylenically unsaturated acid; (c) separating the first liquid product stream obtained in step (b) into a stream comprising the ethylenically unsaturated acid and a stream comprising the reversible diene adducts; and (d) recycling the stream comprising the reversible diene adducts to step (a) , or converting the reversible diene adducts back to the conjugated diene and the ethylenically unsaturated acid and recycling the thus obtained conjugated diene to step (a).
priorityDate 2005-02-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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