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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e945311c7dc7c469bf9eaed4416513cd
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publicationDate 2005-06-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2005052026-A1
titleOfInvention Polyrotaxane and process for producing the same
abstract A process for producing a polyrotaxane in a high yield and at a satisfactory cost without using a large excess of a pseudopolyrotaxane and/or without using a large excess of an activated reagent. The process for polyrotaxane production comprises: a clathration step in which a carboxylated polyethylene glycol which is a polyethylene glycol carboxylated at each end is mixed with cyclodextrin molecules to obtain a pseudopolyrotaxane which comprises cyclodextrin molecules which include the carboxylated polyethylene glycol in their spaces as if the cyclodextrin molecules are spitted with the carboxylated polyethylene glycol; and a blocking step in which the pseudopolyrotaxane is reacted with blocking groups having -NH2 or -OH to obtain a polyrotaxane terminated at each end by a -CO-NH-(blocking group) or -CO-O-(blocking group).
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