http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2005047354-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_7a31b6a8b0338c41a0d80f00793787d2 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0d4071d61bd31b91982c9bd0b2e4def8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_cf2a3a767ae32dfcda1f4e6642aeadc9 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_82a1ad1b20c1ac34fdf303307f62c103 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_8b97a01b206d24aabcbcff779b68e3e4 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F2438-03 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F293-005 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F293-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F2-38 |
filingDate | 2004-11-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_227698ff780dfb831b8aa12a21dde682 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ea0eeaf89f2b502d14a477092c34a71d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_30ebfeff465ccb14c98cd4d21ff4a95f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e048a1e4450c01827cb17b0725f785a7 |
publicationDate | 2005-05-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | WO-2005047354-A1 |
titleOfInvention | Process for producing homo-and co-polymers by raft emulsion polymerization |
abstract | A novel process to produce homo- and co-polymers by RAFT polymerization in emulsion is here disclosed. The invention mixes to different existing technologies: emulsion polymerization and living free radical polymerization (LFRP) by RAFT. Emulsion provides the necessary radical segregation in order to reduce bimolecular terminations and to increase the polymerization rate. The presence of the RAFT agent assures the living mechanism. RAFT agents are often characterized by very low water solubility and, once put in emulsion, they do not participate the reaction. On the other hand, compounds able to form a water soluble complex with the RAFT agent (e.g., cyclodextrins) can help the transport across the water phase of the RAFT agent to the polymer particles. Accordingly, chains can grow through the entire process in a highly controlled way. This generally leads to the production of low polydispersity polymers with well defined structure and end functionalities. It is worth noting that, since the RAFT reaction does not affect the radical concentration in the particle, the same polymerization rate as in a conventional polymerization process is obtained. Moreover, since polymer chains are still living at the end of the process, they can be restarted thus producing block copolymers. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-8063144-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-110408294-A |
priorityDate | 2003-11-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 296.