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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0b53825d1ab92fb7c8fc2789bc51184e
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publicationDate 2005-05-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2005044878-A1
titleOfInvention Aqueous emulsion polymerization of functionalized fluoromonomers
abstract A method is provided for aqueous emulsion co-polymerization of two or more fluoromonomers comprising the steps of: 1) forming an aqueous pre-emulsion by mixing a fluoromonomer according to formula I: F2C=CF-R1-SO2X (I) wherein R1 is a branched or unbranched perfluoroalkyl, perfluoroalkoxy or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms and wherein X is F, Cl or Br, together with 0.001-0.9 molar equivalents of a base, in the absence of added emulsifier; and 2) reacting the pre-emulsion with one or more perfluorinated comonomers in the absence of added emulsifier so as to form a fluoropolymer latex comprising a fluoropolymer wherein more than 1 mol% of monomer units are derived from the fluoromonomer according to formula I. In another aspect, the present invention provides a fluoropolymer derived from the fluoropolymer latex made according to the method of the present invention which is free of added emulsifier. In another aspect, the present invention provides a polymer electrolyte membrane comprising the fluoropolymer made according to the method of the present invention which is free of added emulsifier.
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2018189090-A1
priorityDate 2003-10-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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