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filingDate 2004-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fe467461b8429b99f9eec5c64d61aa6e
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publicationDate 2004-08-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-2004072149-A1
titleOfInvention Method for the production of polymethylvinylsiloxane resins with recycling of volatile oligoorganosiloxanes
abstract The invention relates to the field of silicon resins, particularly polymethylvinylsiloxane resins. The invention more specifically relates to a method for the production of polymethylvinylsiloxane resins comprising at least two different types of siloxy motifs R3SiO1/2 (motif M) and SiO4/2 (motif Q, optionally Q<OH>), characterized in that said method comprises the following steps: a) production of a siloxane resin comprising motifs Q by acidic hydrolysis of a siloxane resin precursor, preferably an alkaline silicate; b) functionalization of the siloxane resine obtained in step a) with halogenosilanes in the presence of an apolar solvent, said functionalization generating sub-products including volatile oligosiloxanes (silox); c) recovery of silox produced in step b) in a solution in the apolar solvent; and d) rearrangement of the resin functionalized in step b) with the aid of a strong base in order to eliminate the silanols, also characterized in that at least one part of the silox produced during step b) and recovered in step c) are recycled.
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priorityDate 2003-02-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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