abstract |
A process in which a heterocyclic alcohol is oxidized to produce a heterocyclic aldehyde with high selectivity in high yield. The process comprises reacting a heterocyclic compound having per molecule at least one hydroxymethyl group bonded to a carbon atom of the heterocycle with a hypohalogenous acid salt in the presence of a base to oxidize the hydroxymethyl group to thereby produce the corresponding heterocyclic aldehyde, wherein the reaction is conducted in the presence of a 2,2,6,6-tetramethylpiperidin-1-oxyl derivative having per molecule two or more 2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl groups. |