http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-03076494-A1

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filingDate 2003-03-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_58a51147f342e126c1c6473c60bc0348
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publicationDate 2003-09-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-03076494-A1
titleOfInvention Method for the production of polytetrahydrofuran with a reduced cyclical oligomeric ether content
abstract The invention relates to a method for producing polytetrahydrofuran (PTHF) or tetrahydrofuran (THF) copolymers having an average molecular weight of 650 to 6000 and a cyclical oligomeric ether content of less than 1 percent by weight by means of a treatment with a solvent. The inventive method is characterized by the following steps: a) PTHF or THF copolymers is/are extracted in one or several steps with an aliphatic, linear or branched, cycloaliphatic or olefinic hydrocarbon containing 1 to 15 hydrocarbon atoms, mixtures of said hydrocarbons, or mixtures containing at least 50 percent by weight of said hydrocarbons at temperatures ranging from 20 to 120° C; b) the PTHF phase or THF copolymer phase is separated from the hydrocarbon phase; c) the PTHF phase or THF copolymer phase is largely liberated of hydrocarbon; d) the hydrocarbons are separated from the hydrocarbon phase obtained in step b) by means of distillation; and e) the mixture of cyclical oligomeric ethers and linear PTHF oligomers or oligomeric THF copolymers resulting from step d) is cat-cracked back to THF, and THF is optionally returned to polymerization.
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priorityDate 2002-03-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 36.