http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-0249010-A2

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filingDate 2001-12-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_8e689d3eb1e0c9b1c3e1982a59b89ce0
publicationDate 2002-06-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-0249010-A2
titleOfInvention Lightfast limited replay disk and method of use
abstract An optically readable media (10) has an information-encoding layer (16) and at least one color-forming layer (12) that embodies an optical readout-limiting mechanism. In a first embodiment the at least one color-forming layer contains an additive that does not interfere with the optical readability of hte media for a duration of a readout period. The additive, upon eyposure to a source of optical radiation that is suitable for reversing the color-forming layer from an optical radiaiton that is suitable for reversing the color-forming layer from an optical readout inhibiting state to an optical readout enabling state, undergoes a transformation that maintains the color-forming layer in the optical readout inhibiting state. More specifically, exposure to the source causes the color-forming layer to photobleach and athe additive to oxidize, where the oxidation of the additive permanently inhibits the optical readability of the media. The additive may be a leuco dye. In one embodiment the color-forming layer is comprised of 3-[2,3-bis(4-diethylaminophenyl)vinyl]-6-dimethylaminophthalide and the additive is comprised of benzoyl leucomethylene blue. In a further embodiment the additive is placed into a protective layer (18) that overlies the color-forming layer.
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