http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-0222538-A3

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filingDate 2001-09-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c3a90ba207d281c218cf66f194ede399
publicationDate 2003-08-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber WO-0222538-A3
titleOfInvention Process and intermediate compounds for the preparation of pesticidal fluoroolefin compounds
abstract A two-step process for the preparation of fluoroolefin compounds of formula (I) wherein R is hydrogen or alkyl, and R1 is alkyl or cyclopropyl, or R and R1 are taken together with the carbon atom to which they are attached to form a cyclopropyl group; Ar is phenyl or naphthyl both of which are optionally substituted; Ar1 is phenoxyphenyl, biphenyl, phenyl, benzylphenyl, or benzoylphenyl, all of which may be optionally substituted, comprising reacting fluorobromoolefin compounds of formula (II) with organozinc compounds of formula (III) (BrZnCH¿2Ar?1) or (IV) (Zn(CH¿2Ar?1)2) in the presence of a palladium catalyst and a solvent, which compounds of formula (II) are obtained by reacting aldehyde compounds of formula (V) with (a) fluorotribromomethane, (b) a tri(substituted)phosphine or a hexaalkylphosphoramide or a mixture thereof, and (c) zinc, in the presence of a solvent, compounds of formula (II).
priorityDate 2000-09-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 40.