http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-0194329-A8
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_1d73b2121667d3e9499af09d77911e00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_7c3abccac7bae9414dc8ce09b2d192dc http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_7d38c1958dad1a5b0be1982f0e787575 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_dac0916a5e956990c79e077ea82343cd http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_966b09afca7edd36f13efd2f5dde6ea3 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-77 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-83 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-83 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-79 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-77 |
filingDate | 2001-05-09-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b38d48e2f59b9319ab082999062a4a8d http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_51ce2370243cc79b1a06baf16157557e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_aeab36d3aca7cd6629de990c4908738f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_004290c5b6f04c91a45722b51983b2aa |
publicationDate | 2003-02-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | WO-0194329-A8 |
titleOfInvention | Method for the production of 2- coumarone and substituted 2-coumarones |
abstract | The invention relates to a method for the production of 2-coumarone or substituted 2-coumarones, whereby cyclohexanone or substituted cyclohexanone is reacted with a carboxyl-containing acylating agent a) to give methyl 2-(2-oxo-cyclohexyl)-2-hydroxyacetate or substituted methyl 2-(2-oxo-cyclohexyl)-2-hydroxyacetates, which are either a1) directly converted to 2-coumarone or substituted 2-coumarones by means of catalytic gas-phase dehydrogenation, or a2) dehydrated by means of azeotropic distillation under basic conditions, or by use of a strong acid, or a strongly acidic ion exchanger to a mixture of methyl 2-oxocyclohexylidenacetate and the enol-lactone of the 2-oxocyclohexylidenacetic acid, or a mixture of substituted methyl 2-oxocyclohexylidenacetate and the enol-lactone of the substituted 2-oxocyclohexylidenacetic acid, which is finally converted in turn by catalytic gas-phase dehydrogenation to 2-coumarone, or substituted 2-coumarones, or b) are directly converted under acidic or basic conditions into a mixture of methyl 2-oxocyclohexylidenacetate and the enol-lactone of 2-oxo-cyclohexylidenacetic acid, or a mixture of substituted methyl 2-oxocyclohexylidenacetate and the enol-lactone of the substituted 2-oxo-cyclohexylidenacetic acid, which is finally converted in turn by catalytic gas-phase dehydrogenation into 2-coumarone or substituted 2-coumarones. |
priorityDate | 2000-06-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 44.