http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9982092-B1

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-52
filingDate 2017-04-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-05-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5e7706efdfd3768a1e04f71517701131
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publicationDate 2018-05-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9982092-B1
titleOfInvention Supercritical carbon dioxide morphologically modified acid-based halloysite catalyst
abstract The efficient production of poly(tetramethylene ether) diacetate [PTMEA] or other diesters, from tetrahydrofuran [THF] is obtained utilizing an acid-based catalyst that is based on a morphologically reconfigured and Bronsted acidity enhanced halloysite derived from a preparation method of using naturally occurring halloysites. More specifically, the method relates to morphological modification of the internal pore structure of halloysites via supercritical carbon dioxide treatment directly applied onto the raw halloysite minerals, that yields highly synergistic and reproducible results of elimination of inaccessible and detrimental extra-small pores. PTMEA is readily converted to poly(tetramethylene ether) glycol (PTMEG) by a transesterification reaction.
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