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filingDate 2014-06-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_bc1ad27ab2802bbbbbaf5a8543e9503c
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publicationDate 2018-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9919470-B2
titleOfInvention Method of preparing a bidirectional shape-memory actuator and method of its use
abstract The present invention is directed to a method of preparing an actuator capable of being repeatedly and reversibly shifted between two freestanding shapes (A, B) under stress-free conditions upon varying a temperature between a temperature T low and a temperature T sep . The method comprising the steps:n (a) providing an actuator consisting of or comprising a covalently or physically cross-linked polymer network, the polymer comprising a first phase having a thermodynamic phase transition extending in a temperature range from T trans,onset to T trans,offset , and an elastic phase having a glass transition temperature T g , with T g <T trans,onset , the polymer having an initial shape; (b) deforming the polymer to a deformation shape at a temperature T prog by applying a stress, where the deformation is adapted to align chain segments of the polymer; (c) setting the polymer to a temperature T low with T low ≤T trans,onset under maintaining the stress as to provide a solidified state of the polymer domains associated with the first phase; (d) heating the polymer to a predetermined separation temperature T sep , with T trans,onset <T sep <T trans,offset , under stress-free conditions as to melt first polymeric domains (AD) of the first phase having a transition temperature in the range between T trans,onset and T sep and to maintain second domains (SD) of the first phase having a transition temperature in the range between T sep and T trans,offset in the solidified state, thus implementing shape A, where shape A geometrically lies between the initial shape provided in step (a) and the deformation shape applied in step (b) and shape B is the shape at T low and lies geometrically between shape A and the shape of deformation of step (b).
priorityDate 2013-06-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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