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filingDate 2014-01-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-02-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2018-02-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9896593-B2
titleOfInvention Polyelectrolyte multilayers having salt-controlled internal structures
abstract A method, and an article made therefrom, of: contacting a substrate with a first solution of first polyelectrolyte chains to form a layer of the first polyelectrolyte on the substrate; and contacting the layer of the first polyelectrolyte with a second solution of second polyelectrolyte chains to form a layer of the second polyelectrolyte. The first polyelectrolyte has a polyanion or polycation chain. The second polyelectrolyte has a polyanion or polycation chain of a charge opposite to that of the first polyelectrolyte. The first solution or the second solution is an aggregate-forming solution comprising an ionic species having at least two discrete sites of a charge opposite to that of the polyelectrolyte chains in the aggregate-forming solution. The ionic species forms, via bridging interactions, aggregates of the polyelectrolyte chains that remain intact in the aggregate-forming solution during the contact.
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