abstract |
Described herein is a composition comprising: a polymer derived from (a) a fluorinated olefin monomer; (b) a highly fluorinated sulfur-containing monomer of the formula: CX 1 X 2 ═CX 3 [(CX 4 X 5 ) w —O—R 1 —SO 2 Y] where X 1 , X 2 , X 3 , X 4 , and X 5 are independently selected from H, Cl, or F; w is 0 or 1; R 1 is a non-fluorinated or fluorinated alkylene group; and Y is selected from F, Cl, Br, I, or OM, where M is a cation; and (c) a polyfunctional monomer comprising at least two functional groups, wherein the functional groups are selected from the group consisting of: (i) a fluorovinyl ether group, (ii) a fluoroallyl ether group, (iii) a fluorinated olefinic group, and (iv) combinations thereof; articles thereof; and a method of making such polymers. |