| abstract |
The present invention provides a cross-linking non-fluoro hydrophobic aqueous polyurethane dispersion, which is produced by selecting a compound comprising alcohols, amines, acids, saturated or unsaturated (double-bonded or epoxidized) aliphatic long chain carbon-carbon groups or polydimethylsiloxane comprising alcohol groups, amines, oxosilane to be reacted with IPDI to obtain a PU prepolymer; adding a compound having tertiary amines to neutralize the carboxylic acid of PU prepolymer and adding water to disperse the PU prepolymer; and adding a ambient temperature cross-linking agent to obtain a cross-linking hydrophobic aqueous PU dispersion of the present invention. The hydrophobic aqueous-based PU resin has no fluorine which is friendly to the environment, and may further self cross-links on its applications on fabric, paper, wood, glass and metal surfaces, respectively on drying at ambient temperature which is energy saving process. Its cross-linking reaction of this hydrophobic PU system that will achieve a long-lasting water repellent surface treatment. |