Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_02fc8b0aa7fd88c3eb85c0889572d326 |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-002 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-847 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-007 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-755 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-1009 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-006 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-322 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T428-2982 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1845 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C22B23-021 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C253-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C255-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-755 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-0053 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-006 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-185 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-2409 |
classificationIPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J35-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J35-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-755 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C22B23-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C253-10 |
filingDate |
2015-03-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2017-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b0b4142b1c67b343437813a93168dd45 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_085b4b26d2a660e97bf7eb55a12e0534 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5dc61d8e0387aafb7668a92aeeb92a10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_182f543602547d34600487c18858ec05 |
publicationDate |
2017-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
US-9687836-B2 |
titleOfInvention |
Nickel form for preparation of catalytic nickel-ligand complexes |
abstract |
A novel nickel particulate form is provided that efficiently forms a zero-valent nickel complex with a phosphorus-containing ligands in an organic liquid to form a hydrocyanation catalyst. Particles in the nickel particulate form comprise nickel crystallites. For example, the nickel particulate form can have a BET Specific Surface Area of at least about 1 m 2 /gm; an average crystallite size less than about 20-25 nm, the nickel particulate form can have at least 10% of the crystallites in the nickel form can have can have a diameter (C10) of less than about 10 nm, and/or there are on average at least about 10 15 surface crystallites per gram nickel. A ratio of BET SSA to C50 for the nickel particulate form can be at least about 0.1×10 9 m/gm and preferably at least about 0.4×10 9 m/gm. Methods of preparation and use are also provided. |
priorityDate |
2011-06-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |