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filingDate 2014-06-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2017-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2017-03-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9586873-B2
titleOfInvention Method for the selective production of para-dialkylbenzenes
abstract A method is disclosed for selective simultaneous production of para-xylene, para-ethyltoluene and para-diethylbenzene from a reactant stream containing ethylbenzene and methanol, as an alkylating agent. The process comprises alkylation of the feedstock in a fluidized-bed rector under alkylating conditions, over a modified ZSM-5-based catalyst to produce streams containing above 95% para-isomers of dialkylbenzenes. The method also includes the steps of multilayer silylation to achieve simultaneous selectivity of the para-isomers of dialkylbenzenes.
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