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filingDate 2012-08-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2016-12-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_09c21279f025adc55f106c896e63d0c3
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publicationDate 2016-12-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9512267-B2
titleOfInvention Catalyst systems based on phenolate complexes for immortal ring-opening polymerization of cyclic esters and carbohydrates
abstract A method can include immortal ring-opening homopolymerisation of cyclic carbonates or cyclic esters in the presence of a catalytic system, or sequential two-step ring-opening block copolymerisation of one or more cyclic monomers selected from cyclic carbonates or cyclic esters in the presence of the catalytic system. The catalytic system can include a phenolate supported metallic complex. The catalytic system can also include an alcohol or a primary amine containing aliphatic and/or aromatic moieties. The alcohol or primary amine can be present in a molar ratio with respect to the metallic complex that is larger than 1.
priorityDate 2011-09-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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