Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_cd66ef85c1c17f957dca2c6bc7daf481 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_56ee98e751442d9006dddd9f90e54edc http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_6ee25bcf5b41efe7d58362ab2d2aef12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_dc6edecd33304a8a9581a130e4f6891c |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-40 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D493-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C231-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C213-00 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D493-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D493-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C213-00 |
filingDate |
2016-03-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2016-10-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_52aedf1cf8dd25a362bb7a94163b3d7a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_34794b7fcf9e74bf408e731a748c8530 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ad649515b182ddcf4f76dcef9dc543de |
publicationDate |
2016-10-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
US-9463450-B1 |
titleOfInvention |
Polymeric acid catalysis |
abstract |
A highly fluorinated polymer is very useful as an acid catalyst. The highly fluorinated polymer has at least two repeating unit types that are the polymerized derivatives of a perfluorinated cyclic or cyclizable compound and a highly fluorinated vinyl ether compound having a sulfur containing functional group. The polymer can be formed by radical copolymerization of the fluorinated monomers with the sulfur-containing functional group in sulfonyl fluoride form (—SO 2 F) that is subsequently converted to sulfonic acid form (—SO 3 H). The highly fluorinated polymer can be used to advantage in a solution comprising an aprotic, polar organic solvent that has a dielectric constant of at least 15 and preferably is free of hydroxyl functional groups. Suitable solvents are those in which the polymer is soluble to at least 1 wt %. Hydroxyl group-containing protic, polar organic solvents are less preferred. The highly fluorinated polymer can be an effective heterogeneous catalysts when used in form of solid, fine particles insolubly suspended in or in contact with a fluid reaction mass. |
priorityDate |
2015-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |