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filingDate 2014-06-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2016-09-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_51ad2d636e7646c6d25165f3cf76638c
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_fe083f085dbb7a8791b5a97d3c5f6c35
publicationDate 2016-09-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9440197-B2
titleOfInvention Crosslinked thermally rearranged poly(benzoxazole-co-imide), gas separation membranes comprising the same and preparation method thereof
abstract Provided is a crosslinked thermally rearranged poly(benzoxazole-co-imide) obtained through the transesterification crosslinking of an ortho-hydroxy polyimide copolymer and a diol compound, followed by thermal rearrangement, a gas separation membrane (excluding a membrane for flue gas separation), and a method for preparing the same. The crosslinked thermally rearranged poly(benzoxazole-co-imide) according to the present invention allows less packing of polymer chains and has a structure with a larger space, and thus shows increased possibility of permeation and diffusion of small molecules therethrough. In addition, the gas separation membrane (with the proviso that a membrane for use in flue gas separation is excluded) including the crosslinked thermally rearranged poly(benzoxazole-co-imide) according to the present invention has excellent gas permeability and selectivity, and particularly shows gas separation quality in terms of carbon dioxide/methane separation corresponding to a level exceeding the so-called 2008 upper bound.
priorityDate 2013-07-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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