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grantDate 2016-07-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2016-07-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-9384867-B2
titleOfInvention Flexible, semiconducting nanocomposite materials based on nanocrystalline cellulose and polyaniline
abstract A new approach is conceived for the development of organic polymeric conducting materials synthesized from nanocomposites of nanocrystalline cellulose (NCC) and polyaniline (PANI). The process involves oxidative-radical polymerization of aniline in the presence of NCC using either in situ or emulsion polymerization. The resulting NCC-PANI nanocomposite material can be obtained in film or powder form and exhibits electrical conductive properties typical of semiconducting materials. Unlike PANI, a brittle conductive polymer, NCC-PANI nanocomposite materials can be engineered to possess significant flexibility, strength and/or hardness as a result of the NCC acting as a reinforcing scaffold. Depending on the preparation conditions, electrical conductivities for the NCC-PANI nanocomposite materials prepared according to this disclosure range from 9.98×10 −5 to 1.88×10 −2 S·cm −1 ; they could also have hardness ≧0.189 GPa or be formed into flexible films of tensile strength of the order of 9.74 MPa and stretch of the order of 0.54%. These unique electrical and mechanical properties render these materials suitable for use in a variety of value-added industrial products, such as batteries, electronics, electrical sensors, separation membranes, anti-static coatings for aerospace applications, as well as anti-corrosive coatings for automotives and other industrial applications.
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