Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_906c940cf0e52f5014937471bdcf4754 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_8f031ac68d020f88277885985c4013e3 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_ff7eec30e4cde3f9cfa97726d3f69eb8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_a696ab2bea45f33018b2eb8a3e20401a |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2110-0008 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G2101-00 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-485 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C11C3-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G65-2654 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C11C3-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G65-2615 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C43-00 |
filingDate |
2006-04-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2014-04-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7ddc49f0755b887e9cd0912cce6bda11 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cf297ee621a76197824813434f51ed66 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a8646a876fe7a9bf54970a1f00c9c529 |
publicationDate |
2014-04-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
US-8692030-B1 |
titleOfInvention |
Biobased-petrochemical hybrid polyols |
abstract |
A method of making a biobased-petrochemical hybrid polyol is provided. This method includes reacting a cyclic ether with a vegetable oil-based polyol in the presence of a cationic catalyst or a coordinative catalyst that includes a vegetable oil-based polyol ligand to form the biobased-petrochemical hybrid polyol. The biobased-petrochemical hybrid polyol that is created has a number average molecular weight of about 3,000 to about 6,000 and has a structure that is about 22% to about 36% biobased. In one aspect of the present invention, the cyclic ether is propylene oxide, and the propoxylated polyol formed from the propylene oxide and vegetable oil-based polyol is then reacted with ethylene oxide in the presence of a superacid catalyst to create a block copolymer with a terminal polyethylene oxide block having a high percentage of terminal primary hydroxyl groups. If the cyclic ether is a homogeneous mixture of ethylene oxide and propylene oxide, then propylene oxide-ethylene oxide random copolymers are formed by polyaddition to vegetable oil polyols. The biobased-petrochemical hybrid polyol may be reacted with an isocyanate so as to create a flexible polyurethane that has good hydrolytic resistance. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10301239-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/WO-2018005538-A2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11613604-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2022380517-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-20190039095-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-10793672-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106661175-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114524728-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-114524728-B http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-112939906-A http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-11390712-B2 |
priorityDate |
2006-04-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |