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filingDate 2009-06-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2014-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c6485610b7662dfc8265eb0969725930
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publicationDate 2014-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-8680230-B2
titleOfInvention Production process of poly(arylene sulfide) whose content of terminal halogen group has been reduced
abstract The invention provides a production process of a poly(arylene sulfide) which contains a step of polymerizing a sulfur source and a dihalo-aromatic compound in an organic amide solvent, said polymerization step containing a phase-separation polymerization step that the polymerization reaction is continued in the presence of a phase separation agent in a phase-separated state, wherein a monohalo-organic compound is added in a proportion of 0.005 to 20 mol per 100 mol of the charged sulfur source into the polymerization reaction system at the time a conversion of the dihalo-aromatic compound has reached 80 to 99% after initiation of the polymerization reaction and before the liquid phase becomes the phase-separated state to be reacted with a formed polymer, and the liquid phase within the polymerization reaction system is then converted to the phase-separated state to continue the polymerization reaction.
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