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publicationDate 2010-06-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-7731919-B2
titleOfInvention Fixed bed reactor for gas-phase catalytic oxidation and processes for producing acrolein or acrylic acid
abstract A fixed bed reactor for gas-phase catalytic oxidation, the fixed bed reactor, comprising a reaction tube filled with a gas-phase oxidation catalyst, wherein a solid acid is placed in an end portion(s) of the reaction tube or between catalyst layers of the catalyst, or mixed in the catalyst; the solid acid is an oxide or a complex oxide containing at least one kind of element selected from the group consisting of aluminum (Al), silicon (Si), titanium (Ti) and zirconium (Zr), and has a shape of sphere, cylindrical column, cylindrical tube, star, ring, tablet or pellet; the catalyst is a complex oxide containing molybdenum (Mo) and bismuth (Bi) or a complex oxide containing molybdenum (Mo) and vanadium (V); and acid strength(H 0 ) of the solid acid meets an inequality: −5.6≦H 0 ≦1.5.
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