http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7468119-B2

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filingDate 2004-09-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2008-12-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7b9de3692a7806e77160c681b3b3be98
publicationDate 2008-12-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-7468119-B2
titleOfInvention Separation of 6-aminocapronitrile and hexamethylenediamine from a mixture comprising hexamethylenediamine, 6-aminocapronitrile and tetrahydroazepine
abstract The invention relates to the field of separation by distillation of 6-aminocapronitrile (ACN) and hexamethylenediamine (HMD) from a mixture containing ACN, HMD, tetrahydrozaepine (THA), adiponitrile (ADN) and low boilers (LB). A method for producing a distillate stream comprising HMD is disclosed, which is suitable for the production of Nylon-6,6. The tails stream from the distillation of the mixture can be further distilled to produce a distillate containing ACN and THA, which is particularly suitable for use in the production of caprolactam and Nylon-6 from the caprolactam. Process conditions of the method of the invention disfavor the production of 2-cyanocyclopentylideneirnine (CPI).
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