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publicationDate 2008-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-7351820-B2
titleOfInvention Process for preparing caprolactam by Beckmann rearrangement
abstract The invention relates to a process for preparing caprolactam by Beckmann rearrangement of cyclohexanone oxime by feeding cyclohexanone oxime to a reaction mixture comprising (i) sulfuric acid (ii) SO 3 and (iii) caprolactam , wherein the SO 3 content of the reaction mixture is between 9 and 20 wt. % and the molar ratio M of the reaction mixture defined as (n so3 +n H2SO4 )/n cap is between 1 and 1.4, wherein n so3 =quantity of SO 3 in reaction mixture, in mol n so3 =quantity of H 2 SO 4 in reaction mixture, in mol n cap =quantity of caprolactam in reaction mixture, in mol.
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