Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_114e4423ec77cbc8dab9d0a98909704e |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-293 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-297 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-29 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-29 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-297 |
filingDate |
2004-03-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2007-10-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_361cb916e015f6519771e9c1811f00e6 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a751222613f0ef3d859aa5b325c832ba http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6d329a4cdc5be54690d8eb624ac7aa32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_13ebbc3b57900332fc605340e8cdf907 |
publicationDate |
2007-10-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
US-7288672-B2 |
titleOfInvention |
Process for preparation of esters of hydroxy tiglic Aldehydes |
abstract |
The present invention relates to a process for the preparation of esters of hydroxy tiglic aldehydes which are the key intermediates for Vitamin-A acetate synthesis and various perfumistic products, said process relates to the hydroformylation of biscarboxylic esters of but-2-ene-1,4-diol, followed by deacetoxylation of its hydroformylation compound, in the presence of heterogeneous catalyst having rhodium complex entrapped, anchored or teethered on the acidic support, said acidic support causes deacetoxylation in the reaction mixture immediately after hydroformylation, to give 100% selectivity to the carboxylic esters of hydroxyl tiglic aldehydes in a single step. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-101642719-B |
priorityDate |
2004-03-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |