http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6872846-B2
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2f8cfa5aee4410611b5c562275c9f8e3 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2603-68 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2603-74 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2602-42 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-14 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B49-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-03 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-05 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-68 |
filingDate | 2001-11-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2005-03-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_c422b2607dc3268332c5b20f483347fc http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_feec9a0a93836de4d089455ca861d387 |
publicationDate | 2005-03-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-6872846-B2 |
titleOfInvention | Process for preparation of tertiary alcohol esters |
abstract | The production process of the present invention comprises a step of allowing a carboxylic acid derivative represented by the formula (1): n n nwherein ring Z is a monocyclic or polycyclic non-aromatic or aromatic ring, and R 1 is a halogen atom or a group represented by the formula (2):n n—OR (2)n nwherein R is a hydrogen atom or a hydrocarbon group, to react with an organometallic compound represented by the formula (3):n nR 2 -M (3)n nwherein R 2 is a hydrocarbon group, and M is a metallic atom which may have a ligand, or the formula (4):n n-MgY (4)n nwherein Y is a halogen atom,n nand a carboxylic acid halide represented by the formula (5): n n nwherein R 3 is a hydrocarbon group or a heterocyclic group, and X is a halogen atom,n nto yield the tertiary alcohol ester represented by the formula (6): n n nwherein Z, R 2 and R 3 have the same meanings as defined above.n n According to the present invention, a tertiary alcohol compound having a tertiary carbon combined with a ring group can be easily and efficiently produced from carboxylic acid derivative which is comparatively cheap and readily available. |
priorityDate | 2000-11-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 210.