http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6774253-B1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_e3b3f4f8df8306f743faf2d4a4af65e1 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10S526-943 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F17-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F19-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F17-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-28 |
filingDate | 2000-01-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2004-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e53b2cd766f66353911249217fb0aa5a |
publicationDate | 2004-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | US-6774253-B1 |
titleOfInvention | Process for the preparation of titanium complexes |
abstract | A new process is disclosed, particularly simple, convenient and practical, for the direct synthesis of titanium complexes of the formula (I): (D)(ZR<1>m)n(A)TiLpXq, wherein (ZR<1>m)n is a divalent group bridging D and A; D is a delocalized pi-bonded moiety, which is bound in an eta<5 >bonding mode to Ti, and is preferably a Cp moiety; A is -O-, -S-, -N(R<2>)- or -P(R<2>)-, wherein R<2 >is hydrogen, alkyl, cycloalayl, aryl, alkylaryl or arylalkl; L are monoanionic sigma ligands selected from alkyl, cycloalkyl, aryl, alkylaryl and arylalkyl groups; m is 1 or 2; n is 1-3; p is 1 or 2, q is 0 or 1 and p+q=2; said process comprises reacting a ligand of formula (H-D)(ZR<1>m)n(A-H) with about 1 molar equivalent of TiX4 in the presence of about (2+p) molar equivalent of LjB or LMgX wherein X is halogen or -OR', B is an alkaline or alkaline-earth metal, and j is 1 or 2. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7077977-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2004254065-A1 |
priorityDate | 1999-06-04-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 288.