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publicationDate 2003-01-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6511588-B1
titleOfInvention Plating method using an additive
abstract A plating method comprising using a plating solution containing an additive satisfying the following conditions:andwherein D is a diffusion coefficient of the additive; kappa is a surface reaction rate of adsorption or consumption of the additive; h is a height of a trench or hole; w is the width of the trench or the radius of the hole; and THETA is a ratio of (plating film growth rate in the presence of additive)/(plating film growth rate in the absence of additive), is suitable for forming the plating metal in the trench or hole having the width of 1 mum or less (trench) or the radius of 1 mum or less (hole) without generating voids, and particularly suitable for producing semiconductor devices, which can have a multilayer structure of copper wiring layers formed on a semiconductor substrate by using the plating conditions, wherein at least one layer of copper wiring layers is plated in different conditions from the rest of the copper wiring layers.
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