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grantDate 2002-09-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0c6e945ea3503103c5793d511c27ae9c
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publicationDate 2002-09-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6452033-B1
titleOfInvention Method of making N-[2-aminoethyl] aminoalkylalkoxysilanes with ethyenediamine salt recycle
abstract A method of preparing 3-[N-(2-aminoethyl)]aminoalkylalkoxysilanes in which ethylenediamine, ethylenediamine hydrochloride salt, and a suitable omega-chloroalkylalkoxysilane are fed to a reactor at a feed ratio of 3-40 moles total ethylenediamine per mole of chloroalkylalkoxysilane under reaction conditions to produce a such aminoalkylalkoxysilane. The proportions of ethylenediamine and ethylenediamine hydrochloride salt are controlled such that a phase containing the diamine salt is present in said reactor separate from a phase containing the aminoalkylalkoxysilane. Following said reaction, the salt phase is separated from the silane phase for recycle to the two phase reactor.
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