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filingDate 1999-01-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2c5e77c62a7d1ed1332e8d48cbecb813
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publicationDate 2001-10-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6296830-B1
titleOfInvention Layered structure manganese dioxide for cathode material in lithium rechargeable cell and process for producing the same
abstract A layered structure manganese dioxide (MnO 2 ) of which oxide lattices are in the pattern of pseudo-hexagonal close packing ( . . . AABB . . . ) and has hexagonal P6 3 /mmc space group or orthorhombic Cmcm space group. The present invention also provides a process for producing said layered structure manganese dioxide (MnO 2 ) which comprises heat treating a mixture of an alkali metal compound and a manganese compound at a high temperature. During the process, bismuth compounds or lead compounds may be added in order to stabilize the layered crystal structure of MnO 2 , or lithium compounds may be added in order to improve the reversibility of charge and discharge. The layered structure MnO 2 is suitable for use as a cathode material in lithium rechargeable cells, since it does not transform into a spinel phase during charge and discharge cycling, thus having an excellent charging and discharging reversibility.
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