http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6277946-B1

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filingDate 2000-05-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2001-08-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3f28eaa8e9ed76c7ed3dfe33791ee50e
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publicationDate 2001-08-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber US-6277946-B1
titleOfInvention Method for preparation of polycarbonates
abstract A method is provided for the preparation of polycarbonates by the reaction of a diaryl carbonate, such as DPC and a dihydric phenol, such as BPA. The method utilizes the steps of successively processing the diaryl carbonate and the dihydric phenol in a melt in a first reaction stage, a second reaction stage and at least a first polymerization stage, and shifts the processing conditions such that the desired low viscosity/high end-cap product is obtained. This is achieved by having the ratio of diaryl carbonate to dihydric phenol in the melt prior to the first reaction stage greater than 1.08; and by controlling the temperature and residence time in the first polymerization stage are selected to provide a polycarbonate product having a melt flow rate at 250° C. of greater than 10 g/10 min and an end-cap level of at least 90%. The method of the invention can be used in a linear manufacturing process, in which there is one product produced. The method of the invention can also be incorporated into a multi-line manufacturing process for the simultaneous production of more than one product. Thus, a stream of product produced from the first polymerization stage may be split into two or more lines which are further processed to produce, for example, a low viscosity, high end-cap product and a medium viscosity, moderate end-cap product.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7999056-B2
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-7279544-B2
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http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2021347939-A1
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2005209434-A1
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2005131197-A1
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2010273973-A1
priorityDate 2000-02-18-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 41.