Predicate |
Object |
assignee |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_33dafb5bbc2ec47ebcb7becbbe60f704 |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-09 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C29-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C11B9-0019 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C11B9-0061 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C33-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C69-007 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C11B9-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-007 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-145 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-30 |
filingDate |
1999-04-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2000-12-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_827eb2aa944b32b93bccdd31ce5edd78 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_70da5fbf3a20ea20821a9570b5ca4289 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1c9c035603cbea64beb8be1300cba519 |
publicationDate |
2000-12-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
US-6159928-A |
titleOfInvention |
Cis-configurational unsaturated ester, process for producing the same, and fragrance composition containing the same |
abstract |
The present invention provides a cis-configurational unsaturated ester represented by the formula (1) (where R is a methyl group or a phenyl group, and n is 1 or 2) and also provides a fragrance composition containing the cis-configurational unsaturated ester in an effective amount. The cis-configurational unsaturated ester represented by the formula (1) can be produced by reacting a cyclic vinyl ether represented by the formula (2a) (where n is defined as above) with a Grignard reagent represented by the formula (3a)RMgX(3a)(where R is defined as above, and X is a chlorine atom, a bromine atom or an iodine atom) in the presence of a triarylphosphine and not more than 0.05 mol of a nickel compound per one mole of the cyclic vinyl ether represented by the formula (2a) to give a cis-configurational unsaturated alcohol represented by the formula (4a) (where n and R are defined as above); and subjecting this cis-configurational unsaturated alcohol to acylation with acetic acid or a derivative thereof to give the cis-configurational unsaturated esters represented by the formula (1). |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2003147972-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9107841-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2003078186-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2013109613-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-2003215690-A1 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-8006336-B1 |
priorityDate |
1998-04-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |